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- W2033348009 abstract "The asymmetric reduction of poly(isopropenyl methyl ketone ) via hydrosilylation gave a new optically active polymer, poly(3-methyl-3-buten-2-ol). The hydrosilylation was carried out with diphenylsilane and a rhodium(I) catalyst containing a chiral phosphine ligand. The effects of the reaction conditions on the optical rotation of the polymer formed were studied in detail. The highest specific rotation ([α]D20) reached was +18.4°, and was attained by the hydrosilylation in 1,4-dioxane at 30°C. On the other hand, both pinacolone (as a monomeric ketone) and a 1: 1 copolymer of isopropenyl methyl ketone with styrene produced the corresponding alcohols having negative small rotations (ca. −3°)." @default.
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- W2033348009 date "1981-06-01" @default.
- W2033348009 modified "2023-10-18" @default.
- W2033348009 title "Asymmetric Reduction of Poly(isopropenyl methyl ketone) via Rhodium(I)-Catalyzed Hydrosilylation" @default.
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- W2033348009 doi "https://doi.org/10.1295/polymj.13.573" @default.
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