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- W2033452316 abstract "Temperature-induced decomposition of methanethiol (CH 3 SH) on the Pt(111) surface causes the formation of two new surface intermediates, thiomethoxy (SCH 3 ) and thioformaldehyde (SCH 2 ). Both the adsorbed thiomethoxy (SCH 3 ) and thioformaldehyde (SCH 2 ) intermediates exhibit novel tilted geometries. The partial decomposition of SCH 3 to form a stable SCH 2 species contrasts with the behavior of adsorbed methoxy (OCH 3 ) which decomposes completely with increasing temperature to form CO and H 2 on the Pt(111) surface." @default.
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- W2033452316 date "1985-10-01" @default.
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- W2033452316 title "Observation of novel intermediates from CH3SH decomposition on Pt(111) with HREELS and NEXAFS" @default.
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- W2033452316 doi "https://doi.org/10.1016/0009-2614(85)87059-7" @default.
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