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• W2033462830 endingPage "884" @default.
• W2033462830 startingPage "875" @default.
• W2033462830 abstract "A series of substituted 2,5-dioxo-1,2,3,4,5,5,7,8-octahydroquinolines have been synthesised from Meldrum's acid and dimedone in the presence of different aldehydes by following an approach similar to the one developed by Hantzch. The structure of these compounds has been thoroughly studied by X-ray crystallographic analysis and semiempirical (AM1) and ab initio (HF/3–21G) methods, and two favoured conformations are possible. A good agreement is found between the theoretical and experimental values. The most stable conformation (A) in the solid state is also that favoured in solution, according to the proton coupling constant determined from Karplus' and Altona's equations and 1H NMR spectroscopic experiments." @default.
• W2033462830 created "2016-06-24" @default.
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• W2033462830 date "1999-01-01" @default.
• W2033462830 modified "2023-10-13" @default.
• W2033462830 title "A joint experimental and theoretical structural study of novel substituted 2,5-dioxo-1,2,3,4,5,6,7,8-octahydroquinolines" @default.
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• W2033462830 doi "https://doi.org/10.1016/s0040-4020(98)01078-3" @default.
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