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- W2033478144 abstract "Amperometric determination of electroactive species not requiring calibration described in this work is based on separation of linear and spherical parts of limiting diffusion current of a determined substance to the hemispherical Hg-semimicroelectrode (radius 37.5 μm). Charges transfered by these two components of current during experiment are comparable for semimicroelectrodes and the determination error is acceptably low (< 10%) for concentration interval 50–500 μmol dm−3. The calibrationless amperometric determination was verified with cadmium and lead. A new way of calculating optimum value of electrode radius to minimize the determination error is also presented." @default.
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- W2033478144 date "1995-04-01" @default.
- W2033478144 modified "2023-09-25" @default.
- W2033478144 title "Absolute (calibrationless) chronoamperometric determination with a mercury hemispherical semimicroelectrode" @default.
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- W2033478144 doi "https://doi.org/10.1002/elan.1140070405" @default.
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