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- W2033486542 abstract "Syntheses of the ring B fragments (+)-pederol dibenzoate (2) and (±)-benzoylpedamide (3) of the insect toxin pederin (1) are described. An intramolecular directed aldol condensation was used to construct the tetrahydropyran ring in (+)-pederol dibenzoate (2). Better stereocontrol in the synthesis of (±)-benzoylpedamide (3) was achieved in which the stereochemistry at C-11 was introduced by a conjugate addition of TMSCN to the dihydropyranone (31). The synthesis of (±)-pederin from (±)-(3) and the ring A. fragment (±)-benzoylselenopederic acid (38) is described." @default.
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- W2033486542 date "1990-01-01" @default.
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- W2033486542 title "Studies related to the synthesis of pederin. part 2. synthesis of pederol dibenzoate and benzoylpedamide" @default.
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- W2033486542 doi "https://doi.org/10.1016/s0040-4020(01)81981-5" @default.
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