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- W2033495028 abstract "Abstract The intriguing, earlier observed, temperature shift of the X-band ESR magnetic field H res was studied for powder samples of linear Cu 3 EtBz·2MeOH and Cu 3 BuNaEs·2MeOH trimeric Cu(II) complexes. For Cu 3 BuNaEs·2MeOH, H res changes dramatically at ∼100 K, where a crystallographic phase transition was found by X-ray diffraction. For Cu 3 EtBz·2MeOH, ESR measurements were performed under high pressure. It was observed that H res decreases with increasing pressure but the linewidth increases. Far-infrared absorption measurements were performed as a function of temperature for Cu 3 EtBz·2MeOH and Cu 3 BuNaEs·2MeOH. No clear change of vibration frequencies with temperature was observed. These results agree with the earlier interpretation that the temperature shift of H res is caused by the thermal averaging of ESR lines due to the short spin-lattice relaxation time." @default.
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- W2033495028 date "2001-11-01" @default.
- W2033495028 modified "2023-10-17" @default.
- W2033495028 title "High pressure ESR and other complementary studies of copper trimers with the quartet spin ground state" @default.
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- W2033495028 doi "https://doi.org/10.1016/s0304-8853(01)00456-5" @default.
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