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• W2033508769 endingPage "1909" @default.
• W2033508769 startingPage "1903" @default.
• W2033508769 abstract "The cleavage of poly(uridylic acid) by imidazole buffer was studied recently by Breslow and Labelle, and a bell-shaped profile was observed for the rate vs. buffer protonation state. The reaction, however, was kinetically first-order in buffer (R. Breslow and M. Labelle, J. Am. Chem. Soc., 108, 2655 (1986)). The sequential base-acid mechanism proposed by those authors is in agreement with the expectation based on the stereoelectronic effects. In addition, the alternative sequential acid-base mechanism, which could not be excluded on the basis of their kinetic data, may be excluded based on the stereoelectronic considerations." @default.
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• W2033508769 date "1987-05-01" @default.
• W2033508769 modified "2023-10-16" @default.
• W2033508769 title "Stereoelectronic Control in the Hydrolysis of RNA by Imidazole" @default.
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• W2033508769 doi "https://doi.org/10.1246/bcsj.60.1903" @default.
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