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• W2033516942 abstract "Totally 3045 transitions into the 23Πg v = 0−42, J = 0−103, Ω = 0, 1, 2 rovibrational levels have been observed by infrared−infrared double resonance fluorescence excitation and two-photon spectroscopy. Molecular constants including the spin−orbit interaction parameters are obtained. Although the K2 23Πg state dissociates to the 4s + 3d atomic limit, it is strongly mixed with the 3P ionic states in the range of the potential well. This mixing results in a relatively large equilibrium internuclear distance Re = 5.254 Å and a larger spin−orbit constant A0 ∼ 14.17 cm-1 than that of the atomic limit −2.33 cm-1. Strong perturbations of the 23Πg levels observed are attributed to the spin−orbit coupling with the state." @default.
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• W2033516942 date "2006-09-12" @default.
• W2033516942 modified "2023-09-25" @default.
• W2033516942 title "The K₂ 2³Π_g State: New Observations and Analysis" @default.
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• W2033516942 doi "https://doi.org/10.1021/jp063266m" @default.
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