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- W2033546016 abstract "To develop a possible structural model for molecular arrangement in Langmuir–Blodgett (LB) films of 2-alkyl-7,7,8,8-tetracyanoquinodimethane (alkyl-TCNQ) the molecular and crystal structures of 2-dodecyl-7,7,8,8-tetracyanoquinodimethane (dodecyl-TCNQ) have been determined by X-ray single-crystal analysis. The compound crystallizes in the triclinic space group P1- with Z = 2. The molecule consists of the planar TCNQ moiety and the dodecyl chain having all-trans conformation. In the crystals the TCNQ fragments make a stacking structure in a head-to-head manner across the centers of symmetry to form a double layer of TCNQ groups. The dodecyl chains protrude oppositely from the TCNQ layers and are assembled to form a close-packed layer, being interdigitated with each other. In this way, the TCNQ moieties and the dodecyl groups form layers alternately. This molecular arrangement in the crystal provides new insight into the structure of the LB films of alkyl-TCNQ." @default.
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- W2033546016 date "2001-11-01" @default.
- W2033546016 modified "2023-09-24" @default.
- W2033546016 title "Crystal and Molecular Structures of 2-Dodecyl-7,7,8,8-tetracyanoquinodimethane" @default.
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- W2033546016 doi "https://doi.org/10.1246/bcsj.74.2019" @default.
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