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- W2033548892 abstract "Rate of solvent extraction of Fe3+ in aqueous perchlorate solutions with trifluoroacetylacetone into carbon tetrachloride is measured. This rate is lower than that of formation of the first complex in the aqueous phase which controls the whole process and the difference between the two rates is very much affected by the chemical equilibria among the complexes in the system. Furthermore, the dependence of the rate on the reagent and hydrogen ions changes by a change in their concentration in the aqueous phase. This is explained in terms that a part of the complexes formed are not extracted and the proportion of the amount of the whole complexes formed to that extracted into the organic phase is not constant." @default.
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- W2033548892 date "1987-04-01" @default.
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- W2033548892 title "Effect of Chemical Equilibria on Rate of Solvent Extraction of Iron(III) with Trifluoroacetylacetone" @default.
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- W2033548892 doi "https://doi.org/10.2116/analsci.3.117" @default.
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