Matches in SemOpenAlex for { <https://semopenalex.org/work/W2033596125> ?p ?o ?g. }
Showing items 1 to 96 of
96
with 100 items per page.
- W2033596125 endingPage "1954" @default.
- W2033596125 startingPage "1949" @default.
- W2033596125 abstract "A novel poly(triazol-1-yl)alkane ligand, bis(3,5-dimethyl-1,2,4-triazol-1-yl)methane CH2(3,5-Me2Tz)2, has been synthesized under phase transfer catalytic conditions. This ligand as well as bis(1,2,4-triazol-1-yl)methane CH2Tz2 and 1,2-bis(1,2,4-triazol-1-yl)ethane (CH2)2Tz2 reacts with diphenyltin(IV) halides to yield novel five- and six-coordinate diorganotin complexes. The crystal structure of (CH2Tz2)SnPh2Br2 determined by X-ray analysis shows that bis(triazol-1-yl)methane coordinates to the tin atom through exodentate nitrogen atoms on the 4-position of triazole rings to form linkage coordination polymers, which leads to a bridging instead of a general chelating metal coordination. Possibly owing to the hindrance of methyl groups in the triazole ring of CH2(3,5-Me2Tz)2, this ligand is a weaker donor to an organotin acceptor than CH2Tz2. In the hydrolysis product [SnPh2Br2(H2O)]·(CH2(3,5-Me2Tz)2), the tin atom is five-coordinate with a trigonal bipyramid geometry, and the aqua ligand is simultaneously connected to the exonitrogen atoms of two adjacent CH2(3,5-Me2Tz) molecules through hydrogen bonding." @default.
- W2033596125 created "2016-06-24" @default.
- W2033596125 creator A5001869015 @default.
- W2033596125 creator A5037518762 @default.
- W2033596125 creator A5048751740 @default.
- W2033596125 creator A5059226855 @default.
- W2033596125 creator A5082089094 @default.
- W2033596125 creator A5090424198 @default.
- W2033596125 date "2000-09-01" @default.
- W2033596125 modified "2023-10-12" @default.
- W2033596125 title "Novel five- and six-coordinate diorganotin(IV) complexes with bis(triazol-1-yl)alkanes: linkage coordination polymers" @default.
- W2033596125 cites W1968131637 @default.
- W2033596125 cites W1969594163 @default.
- W2033596125 cites W1973966931 @default.
- W2033596125 cites W1977855020 @default.
- W2033596125 cites W1983328900 @default.
- W2033596125 cites W2025419207 @default.
- W2033596125 cites W2026347248 @default.
- W2033596125 cites W2038550916 @default.
- W2033596125 cites W2043901832 @default.
- W2033596125 cites W2047216667 @default.
- W2033596125 cites W2056767962 @default.
- W2033596125 cites W2057688907 @default.
- W2033596125 cites W2059939301 @default.
- W2033596125 cites W2070176182 @default.
- W2033596125 cites W2073133771 @default.
- W2033596125 cites W2086551396 @default.
- W2033596125 cites W2095569650 @default.
- W2033596125 cites W2101748147 @default.
- W2033596125 cites W2148062424 @default.
- W2033596125 cites W2169900560 @default.
- W2033596125 cites W2170621361 @default.
- W2033596125 cites W2949381770 @default.
- W2033596125 cites W4236803905 @default.
- W2033596125 cites W4254109876 @default.
- W2033596125 cites W43519770 @default.
- W2033596125 doi "https://doi.org/10.1016/s0277-5387(00)00457-5" @default.
- W2033596125 hasPublicationYear "2000" @default.
- W2033596125 type Work @default.
- W2033596125 sameAs 2033596125 @default.
- W2033596125 citedByCount "41" @default.
- W2033596125 countsByYear W20335961252017 @default.
- W2033596125 crossrefType "journal-article" @default.
- W2033596125 hasAuthorship W2033596125A5001869015 @default.
- W2033596125 hasAuthorship W2033596125A5037518762 @default.
- W2033596125 hasAuthorship W2033596125A5048751740 @default.
- W2033596125 hasAuthorship W2033596125A5059226855 @default.
- W2033596125 hasAuthorship W2033596125A5082089094 @default.
- W2033596125 hasAuthorship W2033596125A5090424198 @default.
- W2033596125 hasConcept C111592845 @default.
- W2033596125 hasConcept C112887158 @default.
- W2033596125 hasConcept C115624301 @default.
- W2033596125 hasConcept C116569031 @default.
- W2033596125 hasConcept C155647269 @default.
- W2033596125 hasConcept C170493617 @default.
- W2033596125 hasConcept C178790620 @default.
- W2033596125 hasConcept C185592680 @default.
- W2033596125 hasConcept C2777907353 @default.
- W2033596125 hasConcept C32909587 @default.
- W2033596125 hasConcept C55493867 @default.
- W2033596125 hasConcept C71240020 @default.
- W2033596125 hasConcept C8010536 @default.
- W2033596125 hasConceptScore W2033596125C111592845 @default.
- W2033596125 hasConceptScore W2033596125C112887158 @default.
- W2033596125 hasConceptScore W2033596125C115624301 @default.
- W2033596125 hasConceptScore W2033596125C116569031 @default.
- W2033596125 hasConceptScore W2033596125C155647269 @default.
- W2033596125 hasConceptScore W2033596125C170493617 @default.
- W2033596125 hasConceptScore W2033596125C178790620 @default.
- W2033596125 hasConceptScore W2033596125C185592680 @default.
- W2033596125 hasConceptScore W2033596125C2777907353 @default.
- W2033596125 hasConceptScore W2033596125C32909587 @default.
- W2033596125 hasConceptScore W2033596125C55493867 @default.
- W2033596125 hasConceptScore W2033596125C71240020 @default.
- W2033596125 hasConceptScore W2033596125C8010536 @default.
- W2033596125 hasIssue "16-17" @default.
- W2033596125 hasLocation W20335961251 @default.
- W2033596125 hasOpenAccess W2033596125 @default.
- W2033596125 hasPrimaryLocation W20335961251 @default.
- W2033596125 hasRelatedWork W166742481 @default.
- W2033596125 hasRelatedWork W1982466940 @default.
- W2033596125 hasRelatedWork W1991813516 @default.
- W2033596125 hasRelatedWork W2011771056 @default.
- W2033596125 hasRelatedWork W2032477839 @default.
- W2033596125 hasRelatedWork W2038951998 @default.
- W2033596125 hasRelatedWork W2041441622 @default.
- W2033596125 hasRelatedWork W4230148809 @default.
- W2033596125 hasRelatedWork W4385435985 @default.
- W2033596125 hasRelatedWork W2069640639 @default.
- W2033596125 hasVolume "19" @default.
- W2033596125 isParatext "false" @default.
- W2033596125 isRetracted "false" @default.
- W2033596125 magId "2033596125" @default.
- W2033596125 workType "article" @default.