FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2033617203> ?p ?o ?g. }

• W2033617203 endingPage "1020" @default.
• W2033617203 startingPage "1015" @default.
• W2033617203 abstract "The dynamics of the O-antigen part of the lipopolysaccharide from the enterohemorrhagic Escherichia coli O91 has been determined in solution using 13C NMR relaxation measurements at two magnetic field strengths, 9.4 and 14.1 T, thereby facilitating the testing of several dynamical models. The biological repeating unit, consisting of five sugar residues and substituents, could be determined by spectral analysis of different 1H,13C correlations and corroborated by the relaxation data. The site specifically 13C-labeled material was shown to have ∼10 repeating units with a narrow distribution. A model-free analysis of the relaxation data revealed a complex dynamical behavior where the sugar residues could be described by a global correlation time (τm = 5.4 ns), generalized order parameters (S2 ≈ 0.63), and different correlation times for internal motions related to their position in the repeating unit along the polymer (τe ≈ 360−520 ps). One of the sugar residues showed, in addition, a chemical exchange contribution. Furthermore, a substituent on another sugar residue was described by two order parameters (Sf2 = 0.51 and Ss2 = 0.21). The solution dynamics of the polysaccharide are thus described by highly intricate motions, both in amplitude and time scales. These results are of significance in the general description of polysaccharides surrounding bacterial cell surfaces and in the presentation of antigenic epitopes to the immune system of an invaded host." @default.
• W2033617203 created "2016-06-24" @default.
• W2033617203 creator A5030143938 @default.
• W2033617203 creator A5049601494 @default.
• W2033617203 date "2004-03-11" @default.
• W2033617203 modified "2023-10-18" @default.
• W2033617203 title "Dynamics of the <i>Escherichia </i><i>c</i><i>oli</i> O91 O-Antigen Polysaccharide in Solution as Studied by Carbon-13 NMR Relaxation" @default.
• W2033617203 cites W1491771413 @default.
• W2033617203 cites W1584292656 @default.
• W2033617203 cites W1965750889 @default.
• W2033617203 cites W1975270005 @default.
• W2033617203 cites W1976286190 @default.
• W2033617203 cites W1977585173 @default.
• W2033617203 cites W1980217962 @default.
• W2033617203 cites W1986636937 @default.
• W2033617203 cites W1995221243 @default.
• W2033617203 cites W1996598569 @default.
• W2033617203 cites W1997951349 @default.
• W2033617203 cites W2003625632 @default.
• W2033617203 cites W2005168328 @default.
• W2033617203 cites W2017610000 @default.
• W2033617203 cites W2018337005 @default.
• W2033617203 cites W2025717854 @default.
• W2033617203 cites W2025809052 @default.
• W2033617203 cites W2030542329 @default.
• W2033617203 cites W2031875244 @default.
• W2033617203 cites W2049196282 @default.
• W2033617203 cites W2050440606 @default.
• W2033617203 cites W2053770019 @default.
• W2033617203 cites W2056821802 @default.
• W2033617203 cites W2063864597 @default.
• W2033617203 cites W2064225121 @default.
• W2033617203 cites W2073325747 @default.
• W2033617203 cites W2080717344 @default.
• W2033617203 cites W2084307948 @default.
• W2033617203 cites W2089483888 @default.
• W2033617203 cites W2094376596 @default.
• W2033617203 cites W2094798721 @default.
• W2033617203 cites W2098511780 @default.
• W2033617203 cites W2115610267 @default.
• W2033617203 cites W2116852525 @default.
• W2033617203 cites W2125888829 @default.
• W2033617203 cites W2129583295 @default.
• W2033617203 cites W2144709443 @default.
• W2033617203 cites W2152564036 @default.
• W2033617203 cites W2159871566 @default.
• W2033617203 cites W23007144 @default.
• W2033617203 cites W2951182529 @default.
• W2033617203 cites W360295271 @default.
• W2033617203 cites W73765076 @default.
• W2033617203 doi "https://doi.org/10.1021/bm0345108" @default.
• W2033617203 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15132695" @default.
• W2033617203 hasPublicationYear "2004" @default.
• W2033617203 type Work @default.
• W2033617203 sameAs 2033617203 @default.
• W2033617203 citedByCount "25" @default.
• W2033617203 countsByYear W20336172032013 @default.
• W2033617203 countsByYear W20336172032014 @default.
• W2033617203 countsByYear W20336172032016 @default.
• W2033617203 countsByYear W20336172032017 @default.
• W2033617203 countsByYear W20336172032019 @default.
• W2033617203 countsByYear W20336172032021 @default.
• W2033617203 crossrefType "journal-article" @default.
• W2033617203 hasAuthorship W2033617203A5030143938 @default.
• W2033617203 hasAuthorship W2033617203A5049601494 @default.
• W2033617203 hasConcept C100817775 @default.
• W2033617203 hasConcept C104317684 @default.
• W2033617203 hasConcept C163111631 @default.
• W2033617203 hasConcept C169760540 @default.
• W2033617203 hasConcept C178790620 @default.
• W2033617203 hasConcept C185592680 @default.
• W2033617203 hasConcept C2776029896 @default.
• W2033617203 hasConcept C2777108408 @default.
• W2033617203 hasConcept C2781338088 @default.
• W2033617203 hasConcept C547475151 @default.
• W2033617203 hasConcept C55493867 @default.
• W2033617203 hasConcept C71240020 @default.
• W2033617203 hasConcept C8010536 @default.
• W2033617203 hasConcept C86803240 @default.
• W2033617203 hasConceptScore W2033617203C100817775 @default.
• W2033617203 hasConceptScore W2033617203C104317684 @default.
• W2033617203 hasConceptScore W2033617203C163111631 @default.
• W2033617203 hasConceptScore W2033617203C169760540 @default.
• W2033617203 hasConceptScore W2033617203C178790620 @default.
• W2033617203 hasConceptScore W2033617203C185592680 @default.
• W2033617203 hasConceptScore W2033617203C2776029896 @default.
• W2033617203 hasConceptScore W2033617203C2777108408 @default.
• W2033617203 hasConceptScore W2033617203C2781338088 @default.
• W2033617203 hasConceptScore W2033617203C547475151 @default.
• W2033617203 hasConceptScore W2033617203C55493867 @default.
• W2033617203 hasConceptScore W2033617203C71240020 @default.
• W2033617203 hasConceptScore W2033617203C8010536 @default.
• W2033617203 hasConceptScore W2033617203C86803240 @default.
• W2033617203 hasIssue "3" @default.
• W2033617203 hasLocation W20336172031 @default.
• W2033617203 hasLocation W20336172032 @default.
• W2033617203 hasOpenAccess W2033617203 @default.
• W2033617203 hasPrimaryLocation W20336172031 @default.

• next