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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2033642003> ?p ?o ?g. }

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• W2033642003 abstract "The paper presents high resolution Raman investigations of the Q(1) line of H2 in Ar mixture from low density (Doppler regime) to high density (collisional regime) analyzed with a unique line shape profile. Measurements are performed by stimulated Raman gain spectroscopy between 300 and 1000 K in a wide density range (from 0.2 to 11 amagat). All the observed spectral features are accurately described by a unified model recently proposed by two of the authors. This model accounts for a velocity-memory process, not restricted to the usual hard and soft limits. It also includes correlation between velocity- and phase-changing collisions. An exhaustive analysis of various possible mechanisms on the line shape is achieved. These mechanisms are the Dicke narrowing, the radiator speed dependence of the collisional broadening and shifting parameters, the collisionally induced speed-class exchange and the nonimpact effect. The present test shows the high consistency of the unified model, since it allows one to get a remarkable agreement with all the data by using a unique set of parameters. This model should be useful for optical diagnostics at moderate density, as required for combusting media or atmospheric work." @default.
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• W2033642003 date "2000-01-01" @default.
• W2033642003 modified "2023-10-16" @default.
• W2033642003 title "Collisional effects on spectral line shape from the Doppler to the collisional regime: A rigorous test of a unified model" @default.
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• W2033642003 doi "https://doi.org/10.1063/1.480570" @default.
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