Matches in SemOpenAlex for { <https://semopenalex.org/work/W2033689291> ?p ?o ?g. }
Showing items 1 to 85 of
85
with 100 items per page.
- W2033689291 abstract "Zero kinetic energy (ZEKE) photoelectron spectroscopy of the hydroquinone-water (HQW) complex was carried out to characterize its S(1)-S(0) resonantly enhanced multiphoton ionization (REMPI) spectrum in terms of the cis and trans conformers. The ZEKE spectra of the hydroquinone isomers show differences in the Franck-Condon (FC) activity of a few ring modes, viz., modes 15, 9b, and 6b, due to the different symmetries of the two isomers. These modes were used as a diagnostic tool to carry out the categorical assignment of the REMPI spectrum of the HQW complex. It was found that the FC activity of these diagnostic modes in the cationic ground state (D(0)) of the water complex is similar as that of the monomer. The two lowest energy transitions in the REMPI spectrum of the water complex, 33,175 and 33,209 cm(-1), were reassigned as the band origins of the cis and trans hydroquinone-water complexes, which is opposite of the previous assignment. The intermolecular stretching mode (sigma) of the complex shows a long progression, up to v(')=4, in the cationic ground state and is strongly coupled to other observed ring modes. The Franck-Condon factors for different members in the progression were calculated using the potential energy surfaces computed ab initio. These agree well with the observed intensity patterns in the progression. The ionization potential of the trans and cis complexes was determined to be 60,071+/-4 and 60,024+/-4 cm(-1), respectively." @default.
- W2033689291 created "2016-06-24" @default.
- W2033689291 creator A5022633773 @default.
- W2033689291 creator A5051521935 @default.
- W2033689291 creator A5076133674 @default.
- W2033689291 date "2007-09-28" @default.
- W2033689291 modified "2023-09-23" @default.
- W2033689291 title "Zero kinetic energy spectroscopy of hydroquinone-water (1:1) complex: A probe for conformer assignment" @default.
- W2033689291 cites W2015175338 @default.
- W2033689291 cites W2024935880 @default.
- W2033689291 cites W2035989057 @default.
- W2033689291 cites W2046490807 @default.
- W2033689291 cites W2047009506 @default.
- W2033689291 cites W2047346569 @default.
- W2033689291 cites W2063646027 @default.
- W2033689291 cites W2067430494 @default.
- W2033689291 cites W2068241704 @default.
- W2033689291 cites W2083334329 @default.
- W2033689291 cites W2087069476 @default.
- W2033689291 cites W2093645307 @default.
- W2033689291 cites W2128897806 @default.
- W2033689291 cites W2148941593 @default.
- W2033689291 doi "https://doi.org/10.1063/1.2780158" @default.
- W2033689291 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17902913" @default.
- W2033689291 hasPublicationYear "2007" @default.
- W2033689291 type Work @default.
- W2033689291 sameAs 2033689291 @default.
- W2033689291 citedByCount "6" @default.
- W2033689291 countsByYear W20336892912012 @default.
- W2033689291 countsByYear W20336892912013 @default.
- W2033689291 countsByYear W20336892912014 @default.
- W2033689291 countsByYear W20336892912018 @default.
- W2033689291 countsByYear W20336892912021 @default.
- W2033689291 crossrefType "journal-article" @default.
- W2033689291 hasAuthorship W2033689291A5022633773 @default.
- W2033689291 hasAuthorship W2033689291A5051521935 @default.
- W2033689291 hasAuthorship W2033689291A5076133674 @default.
- W2033689291 hasConcept C121332964 @default.
- W2033689291 hasConcept C145148216 @default.
- W2033689291 hasConcept C147192597 @default.
- W2033689291 hasConcept C166950319 @default.
- W2033689291 hasConcept C178790620 @default.
- W2033689291 hasConcept C184779094 @default.
- W2033689291 hasConcept C185592680 @default.
- W2033689291 hasConcept C18705241 @default.
- W2033689291 hasConcept C198291218 @default.
- W2033689291 hasConcept C2777550763 @default.
- W2033689291 hasConcept C32891209 @default.
- W2033689291 hasConcept C32909587 @default.
- W2033689291 hasConcept C62520636 @default.
- W2033689291 hasConcept C69523127 @default.
- W2033689291 hasConceptScore W2033689291C121332964 @default.
- W2033689291 hasConceptScore W2033689291C145148216 @default.
- W2033689291 hasConceptScore W2033689291C147192597 @default.
- W2033689291 hasConceptScore W2033689291C166950319 @default.
- W2033689291 hasConceptScore W2033689291C178790620 @default.
- W2033689291 hasConceptScore W2033689291C184779094 @default.
- W2033689291 hasConceptScore W2033689291C185592680 @default.
- W2033689291 hasConceptScore W2033689291C18705241 @default.
- W2033689291 hasConceptScore W2033689291C198291218 @default.
- W2033689291 hasConceptScore W2033689291C2777550763 @default.
- W2033689291 hasConceptScore W2033689291C32891209 @default.
- W2033689291 hasConceptScore W2033689291C32909587 @default.
- W2033689291 hasConceptScore W2033689291C62520636 @default.
- W2033689291 hasConceptScore W2033689291C69523127 @default.
- W2033689291 hasIssue "12" @default.
- W2033689291 hasLocation W20336892911 @default.
- W2033689291 hasLocation W20336892912 @default.
- W2033689291 hasOpenAccess W2033689291 @default.
- W2033689291 hasPrimaryLocation W20336892911 @default.
- W2033689291 hasRelatedWork W150221835 @default.
- W2033689291 hasRelatedWork W1988059862 @default.
- W2033689291 hasRelatedWork W2011751377 @default.
- W2033689291 hasRelatedWork W2028280321 @default.
- W2033689291 hasRelatedWork W2031920865 @default.
- W2033689291 hasRelatedWork W2055605975 @default.
- W2033689291 hasRelatedWork W2094183573 @default.
- W2033689291 hasRelatedWork W4220658624 @default.
- W2033689291 hasRelatedWork W4223953309 @default.
- W2033689291 hasRelatedWork W4321018681 @default.
- W2033689291 hasVolume "127" @default.
- W2033689291 isParatext "false" @default.
- W2033689291 isRetracted "false" @default.
- W2033689291 magId "2033689291" @default.
- W2033689291 workType "article" @default.