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- W2033706816 abstract "The competitive isomerization and cracking reactions of branched octanes at 373 K on sulfated zirconia were studied in relation with the product distribution expected from bimolecular pathway for n- to isobutane isomerization. The high selectivity in isoalkanes can be rationalized by a rapid equilibration of the initial octyl ions followed by cracking of those ions which generate t-butyl and t-pentyl cations before hydride transfer. However, the overall product distribution suggests a more complex scheme with substantial participation of higher molecular weight intermediates. Mechanistic routes are discussed." @default.
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- W2033706816 date "1999-11-01" @default.
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- W2033706816 title "Isomerization and cracking reactions of branched octanes on sulfated zirconia" @default.
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