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- W2033711561 abstract "Reaction of an α,β-unsaturated acid chloride with the anion of 5,5-dimethyl-1,3-cyclohexane-dione (2) gives either the enol ester (4) or a cyclized product (5), depending upon the reaction conditions. When the acid chloride is in excess, the ester is obtained. When the anion is in excess and the acid chloride is acryloyl or crotonyl, the cyclized product is obtained. A similar cyclized product (9) was formed from acryloyl chloride and an excess of the anion of 4-hydroxy-6-methyl-2-pyrone (8)." @default.
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- W2033711561 date "1969-12-01" @default.
- W2033711561 modified "2023-09-24" @default.
- W2033711561 title "Reaction of α,β-unsaturated acid chlorides with β-diketones. Synthesis of 4,6,7,8-tetrahydro-2H-1-benzopyran-2,5(3H)-diones" @default.
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- W2033711561 doi "https://doi.org/10.1002/jhet.5570060623" @default.
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