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- W2033714314 abstract "2,2,4,4-Tetrakis(trifluoromethyl)-1,3-dithietane (1) in the KF-DMF system was treated with hexafluoropropene in the presence of CuBr to give copper(I) 1,1,2-tris(trifluoromethyl)tetrafluoropropanethiolate (4). A similar reaction of 1 with alcohols in the presence of CuBr or AgNO3 gave copper(I) (6) and silver 1-alkoxy-1-trifluoromethyl-2,2,2-trifluoroethanethiolate (7) respectively. These copper(I) and silver polyfluoroalkanethiolates condensed with aryl or alkyl iodides to afford 1,1,2-tris(trifluoromethyl)-tetrafluoropropyl (8) and 1-alkoxy-1-trifluoromethyl-2,2,2-trifluoroethyl aryl(or alkyl) sulfides (9)." @default.
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- W2033714314 date "1975-01-01" @default.
- W2033714314 modified "2023-09-22" @default.
- W2033714314 title "The Preparation of Several Copper(I) and Silver Polyfluoroalkanethiolates and of Polyfluoroalkyl Aryl (or Alkyl) Sulfides" @default.
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- W2033714314 doi "https://doi.org/10.1246/bcsj.48.361" @default.
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