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- W2033728797 abstract "Abstract Li-rich layered cathode materials with composition of Li 1.2−x Mn 0.54 Ni 0.13 Co 0.13 O 2−x F x (x = 0, 0.02, 0.05, 0.08) are synthesized by co-precipitation method. Powder X-ray diffraction (XRD), scanning electron microscopy (SEM), BET surface area analysis, high-resolution transition electron microscopy (HR-TEM), X-ray photoelectron spectroscopy (XPS) and galvanostatic charge–discharge measurements are employed to investigate the changes in crystal structure, chemical composition, particle morphology and electrochemical performance. Improved electrochemical performance is observed for fluorine doped materials, among which Li 1.15 Mn 0.54 Ni 0.13 Co 0.13 O 1.95 F 0.05 exhibits the best cyclic performance as well as rate capability at room temperature. The discharge voltage plateau is stabilized by F doping due to the retarded layered-to-spinel phase transition, thus a high energy density output of the cell could be maintained. The mechanisms for the improved electrochemical properties of fluorine doped Li-rich layered cathode are also discussed." @default.
- W2033728797 created "2016-06-24" @default.
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- W2033728797 date "2015-06-01" @default.
- W2033728797 modified "2023-10-13" @default.
- W2033728797 title "Retarded phase transition by fluorine doping in Li-rich layered Li 1.2 Mn 0.54 Ni 0.13 Co 0.13 O 2 cathode material" @default.
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- W2033728797 doi "https://doi.org/10.1016/j.jpowsour.2015.02.085" @default.
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