FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2033791955> ?p ?o ?g. }

• W2033791955 endingPage "979" @default.
• W2033791955 startingPage "963" @default.
• W2033791955 abstract "Abstract Numerical simulations of diffusion‐controlled nucleation and growth of garnet porphyroblasts in regionally metamorphosed rocks constrain interfacial energy and rates of nucleation and Al intergranular diffusion. The 13 rocks analysed in this study were collected from seven localities exhibiting a diverse range of crystallization conditions. Kinetic parameters governing nucleation and intergranular diffusion were adjusted iteratively to achieve fits between simulated and natural porphyroblastic textures. Model fits were assessed primarily from textural characteristics precisely measured by high‐resolution X‐ray computed tomography. Interfacial energy for heterogeneous nucleation ranges from 0.007 to 0.255 J m −2 for the sample suite, assuming shape factors in the range 0.01–1.0. Nucleation rates change through space and time due to growth and impingement of Al depletion zones surrounding porphyroblasts. In some models, the overall rock‐wide nucleation rate rises steeply, achieves a steady state, and then falls rapidly as reactants are consumed; in others, the steady state is not achieved, but instead the rate simply peaks before falling. Maximum rock‐wide nucleation rates range from 10 −14.7 to 10 −10.7 nuclei cm −3 s −1 , and maximum local rates range from 10 −13.7 to 10 −9.7 nuclei∙cm −3 s −1 depending on Al supersaturation. Diffusive fluxes of Al are well constrained by the simulated textures, but rates of intergranular diffusion are subject to uncertainties in Al solubility and interconnected porosity. Best estimates of Al diffusivities at 600 °C span 10 −12.3 to 10 −10.5 m 2 s −1 for the sample suite, a narrow range considering natural variability and the uncertainties in solubility and porosity. Eliminating some models suspected of higher uncertainty for these quantities yields diffusivities at 600 °C near 10 −11.0 m 2 s −1 , with dispersion of less than half an order of magnitude. These simulations, which are among the first attempted for regionally metamorphosed rocks, emphasize that: (i) nucleation rates vary markedly in time and space during crystallization; (ii) nucleation extends well beyond equilibrium conditions; (iii) Al diffusivity likely varies over only a narrow range across common metamorphic circumstances; and (iv) better determinations of both Al solubility and interconnected porosity are needed to constrain rates of Al intergranular diffusion more precisely." @default.
• W2033791955 created "2016-06-24" @default.
• W2033791955 creator A5034609282 @default.
• W2033791955 creator A5069601753 @default.
• W2033791955 creator A5075046514 @default.
• W2033791955 date "2013-09-23" @default.
• W2033791955 modified "2023-10-11" @default.
• W2033791955 title "Crystallization kinetics during regional metamorphism of porphyroblastic rocks" @default.
• W2033791955 cites W1490465230 @default.
• W2033791955 cites W1534009691 @default.
• W2033791955 cites W1587919209 @default.
• W2033791955 cites W1604296611 @default.
• W2033791955 cites W1772602716 @default.
• W2033791955 cites W1830358639 @default.
• W2033791955 cites W1844977582 @default.
• W2033791955 cites W1856019848 @default.
• W2033791955 cites W1942059701 @default.
• W2033791955 cites W1965656370 @default.
• W2033791955 cites W1966799498 @default.
• W2033791955 cites W1973547643 @default.
• W2033791955 cites W1981741514 @default.
• W2033791955 cites W1981887551 @default.
• W2033791955 cites W1982137428 @default.
• W2033791955 cites W1985938344 @default.
• W2033791955 cites W1989192163 @default.
• W2033791955 cites W1989869267 @default.
• W2033791955 cites W1993651156 @default.
• W2033791955 cites W1994816727 @default.
• W2033791955 cites W1996577534 @default.
• W2033791955 cites W2004401680 @default.
• W2033791955 cites W2005011320 @default.
• W2033791955 cites W2013011932 @default.
• W2033791955 cites W2014346120 @default.
• W2033791955 cites W2026935596 @default.
• W2033791955 cites W2028471860 @default.
• W2033791955 cites W2034505166 @default.
• W2033791955 cites W2037202219 @default.
• W2033791955 cites W2039061568 @default.
• W2033791955 cites W2042344123 @default.
• W2033791955 cites W2048656907 @default.
• W2033791955 cites W2049035851 @default.
• W2033791955 cites W2051676612 @default.
• W2033791955 cites W2054746210 @default.
• W2033791955 cites W2060956521 @default.
• W2033791955 cites W2061105442 @default.
• W2033791955 cites W2070776398 @default.
• W2033791955 cites W2072345902 @default.
• W2033791955 cites W2078421630 @default.
• W2033791955 cites W2084499501 @default.
• W2033791955 cites W2085454930 @default.
• W2033791955 cites W2085611837 @default.
• W2033791955 cites W2091155174 @default.
• W2033791955 cites W2091462179 @default.
• W2033791955 cites W2093865975 @default.
• W2033791955 cites W2094414093 @default.
• W2033791955 cites W2095520012 @default.
• W2033791955 cites W2099238837 @default.
• W2033791955 cites W2100411277 @default.
• W2033791955 cites W2101330076 @default.
• W2033791955 cites W2110481460 @default.
• W2033791955 cites W2120258362 @default.
• W2033791955 cites W2120865672 @default.
• W2033791955 cites W2125124494 @default.
• W2033791955 cites W2131942907 @default.
• W2033791955 cites W2133103585 @default.
• W2033791955 cites W2136788496 @default.
• W2033791955 cites W2146983995 @default.
• W2033791955 cites W2149198821 @default.
• W2033791955 cites W2163256492 @default.
• W2033791955 cites W2168889067 @default.
• W2033791955 cites W2332768691 @default.
• W2033791955 doi "https://doi.org/10.1111/jmg.12052" @default.
• W2033791955 hasPublicationYear "2013" @default.
• W2033791955 type Work @default.
• W2033791955 sameAs 2033791955 @default.
• W2033791955 citedByCount "24" @default.
• W2033791955 countsByYear W20337919552013 @default.
• W2033791955 countsByYear W20337919552014 @default.
• W2033791955 countsByYear W20337919552015 @default.
• W2033791955 countsByYear W20337919552016 @default.
• W2033791955 countsByYear W20337919552017 @default.
• W2033791955 countsByYear W20337919552018 @default.
• W2033791955 countsByYear W20337919552019 @default.
• W2033791955 countsByYear W20337919552020 @default.
• W2033791955 countsByYear W20337919552021 @default.
• W2033791955 countsByYear W20337919552022 @default.
• W2033791955 crossrefType "journal-article" @default.
• W2033791955 hasAuthorship W2033791955A5034609282 @default.
• W2033791955 hasAuthorship W2033791955A5069601753 @default.
• W2033791955 hasAuthorship W2033791955A5075046514 @default.
• W2033791955 hasConcept C121332964 @default.
• W2033791955 hasConcept C127313418 @default.
• W2033791955 hasConcept C184102282 @default.
• W2033791955 hasConcept C187320778 @default.
• W2033791955 hasConcept C191897082 @default.
• W2033791955 hasConcept C192562407 @default.
• W2033791955 hasConcept C199289684 @default.
• W2033791955 hasConcept C200447597 @default.

• next