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- W2033810408 abstract "The degree of crystallinity of nylon 6 is increased by both steam and dry heat setting, while the diffusion rate of dyes is increased by steam setting and decreased by dry heat setting. These phenomena have been explained in connection with the state of the amorphous regions. This explanation are confirmed from a quantitative analysis of infrared spectra. Heat-set nylon 6 films were deuterated with D2O at 60°C., for 100 hr. in the vapor phase. Integral intensities of ND stretching vibration band on the spectra are calculated from the equation: where I0 and I are the intensity of the incident and the transmitted light respectively, l the thickness, and α the degree of crystallinity. Here K′C represents the number of free NH groups in the amorphous fraction. The value K′C is increased by steam setting and decreased by dry heat setting." @default.
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- W2033810408 date "1965-01-01" @default.
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- W2033810408 title "Steam and heat setting of nylon 6 fiber. IX. Changes in infrared spectra with deuteration of heat-set nylon 6" @default.
- W2033810408 doi "https://doi.org/10.1002/app.1965.070090110" @default.
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