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• W2033819232 abstract "The reactions of Group 9 transition metal pinacolate complexes Cp*M(pin) (M=Co (1), Rh (2), Ir (3)) with heterocumulenes (YCZ) are described. In these transformations the CZ bond of the heterocumulene is cleaved, and the pinacolate ligand is incorporated into an organic heterocycle (pin)CY. In some cases a clean organometallic product of the general formula Cp*MZ2CY is also produced. The regiochemistry of these reactions has been explored and found to follow expected trends, and evidence suggests a mechanism involving initial heterocumulene insertion into an MO bond yielding a 7-membered metallacycle, followed by 1,2 elimination." @default.
• W2033819232 created "2016-06-24" @default.
• W2033819232 creator A5047518475 @default.
• W2033819232 creator A5076333103 @default.
• W2033819232 date "2002-12-01" @default.
• W2033819232 modified "2023-10-16" @default.
• W2033819232 title "Thermal reactivity of Group 9 transition metal pinacolate complexes: heterocumulene cleavage and CO bond formation" @default.
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• W2033819232 doi "https://doi.org/10.1016/s0020-1693(02)01234-3" @default.
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