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• W2033831936 startingPage "3105" @default.
• W2033831936 abstract "This work is aimed to present and validate a thermodynamic model that enables the prediction of vapor−liquid equilibria of refrigerant mixtures of alkanes and hydrofluorocarbons, in the temperature and pressure ranges of interest for refrigeration cycles and heat pump applications. A modified Redlich−Kwong−Soave equation of state is used with Huron−Vidal mixing rules and a modified UNIFAC group-contribution approach for calculating the component infinite-pressure activity coefficients. A new classification of functional groups is suggested, and the values of interaction parameters between groups are provided. These parameters are regressed from selected binary vapor−liquid equilibrium data. A good regression is obtained for all group pairs, with a maximum root-mean-square deviation on relative pressure residuals of 1.86%. The proposed method is totally predictive since only the structure, critical constants, and vapor pressure of pure components are needed in order to calculate thermodynamic properties of refrigerant mixtures. Results for a number of binary and ternary mixtures are reported and compared to available experimental data." @default.
• W2033831936 created "2016-06-24" @default.
• W2033831936 creator A5026952680 @default.
• W2033831936 creator A5081491233 @default.
• W2033831936 creator A5090048159 @default.
• W2033831936 date "1998-05-28" @default.
• W2033831936 modified "2023-09-25" @default.
• W2033831936 title "Group-Contribution Equation of State for the Prediction of Vapor−Liquid Equilibria of Mixtures Containing Hydrofluorocarbons and Alkanes" @default.
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• W2033831936 doi "https://doi.org/10.1021/ie970867e" @default.
• W2033831936 hasPublicationYear "1998" @default.
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