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• W2033959910 abstract "Chiral α-tertiary hydroxyaldehydes are very versatile building blocks in synthetic chemistry. Herein, we report the first examples of a catalytic asymmetric protocol for the synthesis of such compounds from readily available α-halo or α-hydroxy ketones or enol silyl ethers with excellent yields and enantioselectivity. Its synthetic utility is demonstrated in the short, efficient formal synthesis of (S)-oxybutynin. In this process, the chiral ligand controls the regioselectivity as well as the enantioselectivity." @default.
• W2033959910 created "2016-06-24" @default.
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• W2033959910 date "2006-12-20" @default.
• W2033959910 modified "2023-10-17" @default.
• W2033959910 title "Enantioselective Synthesis of α-Tertiary Hydroxyaldehydes by Palladium-Catalyzed Asymmetric Allylic Alkylation of Enolates" @default.
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• W2033959910 doi "https://doi.org/10.1021/ja067342a" @default.
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