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- W2034001471 abstract "Abstract Reversible voltages between chlorine, bromine, and iodine electrodes at platinum and the silver—silver halogenide electrodes in electrolytes containing sodium or potassium salts of the respective halogenides were measured as a function of static pressure up to 2.1 kb at 298.15K. From the resulting reaction volumes and the known partial molal volumes of silver and the silver halogenides the partial molal volumes of the halogenes in aqueous solution were obtained. The partial molal volmes of the diatomic gases in aqueous solution are a smooth function of the intrinsic volumes calculated from bond lengths, analoguos to the much steeper function for monovalent ions. Iodine behaves anomalously. The experimental partial molal volumes are relatively small and the compressibilities are negative. Both paramenters strongly depend on the concentration of iodide in the electrolyte. It is proposed to explain these effects by a theory based on the formation of the complex J 3 − ." @default.
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- W2034001471 date "1982-01-01" @default.
- W2034001471 modified "2023-09-27" @default.
- W2034001471 title "Partial molal volumes of halogens in aqueous electrolyte solutions" @default.
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- W2034001471 doi "https://doi.org/10.1016/0013-4686(82)80063-7" @default.
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