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- W2034002535 endingPage "2872" @default.
- W2034002535 startingPage "2865" @default.
- W2034002535 abstract "Abstract A stereochemical divergent approach for the highly enantioselective synthesis of distinct bicyclic products with multiple stereocenters from a racemate using a single chiral catalyst is disclosed. It is based on switches of the overall reaction pathways in the chiral amine‐catalyzed cascade reactions between racemic γ‐nitro ketones and α,β‐unsaturated aldehydes using different achiral co‐catalysts. The utility of the method is exemplified by the highly diasteroselective switch and stereoconvergent deracemization process by combination of chiral amine and achiral hydrogen‐bond‐donating catalysts." @default.
- W2034002535 created "2016-06-24" @default.
- W2034002535 creator A5043257252 @default.
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- W2034002535 creator A5068124341 @default.
- W2034002535 creator A5079678363 @default.
- W2034002535 date "2012-10-05" @default.
- W2034002535 modified "2023-10-18" @default.
- W2034002535 title "Achiral Co‐Catalyst Induced Switches in Catalytic Asymmetric Reactions on Racemic Mixtures (RRM): From Stereodivergent RRM to Stereoconvergent Deracemization by Combination of Hydrogen Bond Donating and Chiral Amine Catalysts" @default.
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- W2034002535 doi "https://doi.org/10.1002/adsc.201200357" @default.
- W2034002535 hasPublicationYear "2012" @default.