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- W2034004471 abstract "Solid-state grafting polymerization of styrene (St) in polypropylene (PP) reactor granules was conducted with different St load using tertiary-butyl perbenzoate as initiator. The graft copolymers showed higher weight average molecular weight than the original PP when the St load is high enough. A typical graft copolymer was fractionated into six fractions according to crystallinity, and the fractions showed similar St content. Comparing to the original PP, complex viscosity of the grafting products was significantly increased and the tan α value decreased at low frequency. Increasing the grafting degree exerts a positive effect on these changes. These phenomena prove the existence of long chain branches in the grafting products, and St played important roles in the formation of long chain branches." @default.
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- W2034004471 date "2009-05-06" @default.
- W2034004471 modified "2023-10-14" @default.
- W2034004471 title "Structure and Rheological Properties of the Products of Solid-State Graft Polymerization of Styrene in Annealed Polypropylene Reactor Granules" @default.
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- W2034004471 doi "https://doi.org/10.1080/03602550902824317" @default.
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