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• W2034007858 abstract "The local environment of antimony atoms in vitreous samples of the ternary system Sb 2 S 3 -As 2 S 3 -Tl 2 S is studied by 121 Sb Mossbauer spectroscopy. The results have been interpreted by means of EBV (empirical bond valence) and EBLV (empirical bond length valence) calculations. Variations in isomer shifts are attributed to changes in the environment of antimony atoms. The isomer shift is found to be a very sensitive parameter reflecting variations in the mean coordination number and in the mean Sb-S bond length. The results presented here confirm the random substitution of As by Sb in the binary system As 2 S 3 -Sb 2 S 3 and the competitive effects-breaking of As-S-As bridges by Tl and formation of As-S-Sb bridges-in the ternary system Sb 2 S 3 -As 2 S 3 -Tl 2 S, in agreement with previous XAFS studies." @default.
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• W2034007858 date "1997-11-01" @default.
• W2034007858 modified "2023-09-25" @default.
• W2034007858 title "121Sb Mössbauer Study of Sb2S3–As2S3–Tl2S Glasses" @default.
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• W2034007858 doi "https://doi.org/10.1006/jssc.1997.7510" @default.
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