Matches in SemOpenAlex for { <https://semopenalex.org/work/W2034008039> ?p ?o ?g. }
- W2034008039 endingPage "21" @default.
- W2034008039 startingPage "8" @default.
- W2034008039 abstract "Copolymerizations of vinylidene fluoride (VDF) and hexafluoropropene (HFP) were carried out in homogeneous phase with supercritical carbon dioxide up to complete VDF conversion using conventional peroxide initiators. The HFP monomer feed ratios, fHFP, were varied between 0.65 and 0.20. Depending on fHFP amorphous or semi-crystalline copolymers were obtained. fHFP also determines the minimum pressure required to allow for homogeneous phase reactions. For example, HFP-rich copolymerizations in 70 wt.-% CO2 at 100 °C require a pressure of around 500 bar. Further, bulk copolymerizations in homogenous phase were feasible for fHFP = 0.65 at 900 bar up to complete VDF conversion. Copolymerizations in the presence of perfluorinated hexyl iodide carried out at 75 °C gave access to low dispersity polymers. Due to homogeneous phase conditions the use of any surfactants or fluorinated cosolvent is avoided." @default.
- W2034008039 created "2016-06-24" @default.
- W2034008039 creator A5088832793 @default.
- W2034008039 creator A5042237707 @default.
- W2034008039 date "2010-09-20" @default.
- W2034008039 modified "2023-09-26" @default.
- W2034008039 title "Homogeneous Phase Copolymerizations of Vinylidene Fluoride and Hexafluoropropene in Supercritical Carbon Dioxide" @default.
- W2034008039 cites W1976770880 @default.
- W2034008039 cites W1977587111 @default.
- W2034008039 cites W1980405524 @default.
- W2034008039 cites W1980933346 @default.
- W2034008039 cites W1982764133 @default.
- W2034008039 cites W1984267917 @default.
- W2034008039 cites W1990461790 @default.
- W2034008039 cites W2000566803 @default.
- W2034008039 cites W2004716515 @default.
- W2034008039 cites W2005286803 @default.
- W2034008039 cites W2008827436 @default.
- W2034008039 cites W2012062182 @default.
- W2034008039 cites W2014404457 @default.
- W2034008039 cites W2017487779 @default.
- W2034008039 cites W2018955450 @default.
- W2034008039 cites W2019862100 @default.
- W2034008039 cites W2036950904 @default.
- W2034008039 cites W2037205284 @default.
- W2034008039 cites W2047023763 @default.
- W2034008039 cites W2049574518 @default.
- W2034008039 cites W2051370159 @default.
- W2034008039 cites W2062028531 @default.
- W2034008039 cites W2062049927 @default.
- W2034008039 cites W2063762563 @default.
- W2034008039 cites W2072326416 @default.
- W2034008039 cites W2076338813 @default.
- W2034008039 cites W2078015169 @default.
- W2034008039 cites W2080220379 @default.
- W2034008039 cites W2084943916 @default.
- W2034008039 cites W2089888176 @default.
- W2034008039 cites W2102389128 @default.
- W2034008039 cites W2105633702 @default.
- W2034008039 cites W2114209247 @default.
- W2034008039 cites W2140128496 @default.
- W2034008039 cites W2145197657 @default.
- W2034008039 cites W2152731197 @default.
- W2034008039 cites W2312681217 @default.
- W2034008039 cites W2951886133 @default.
- W2034008039 doi "https://doi.org/10.1002/mren.201000031" @default.
- W2034008039 hasPublicationYear "2010" @default.
- W2034008039 type Work @default.
- W2034008039 sameAs 2034008039 @default.
- W2034008039 citedByCount "8" @default.
- W2034008039 countsByYear W20340080392012 @default.
- W2034008039 countsByYear W20340080392014 @default.
- W2034008039 countsByYear W20340080392017 @default.
- W2034008039 countsByYear W20340080392021 @default.
- W2034008039 crossrefType "journal-article" @default.
- W2034008039 hasAuthorship W2034008039A5042237707 @default.
- W2034008039 hasAuthorship W2034008039A5088832793 @default.
- W2034008039 hasConcept C11432220 @default.
- W2034008039 hasConcept C118419359 @default.
- W2034008039 hasConcept C121332964 @default.
- W2034008039 hasConcept C127413603 @default.
- W2034008039 hasConcept C134458231 @default.
- W2034008039 hasConcept C15920480 @default.
- W2034008039 hasConcept C159985019 @default.
- W2034008039 hasConcept C166940927 @default.
- W2034008039 hasConcept C178790620 @default.
- W2034008039 hasConcept C179104552 @default.
- W2034008039 hasConcept C185592680 @default.
- W2034008039 hasConcept C188027245 @default.
- W2034008039 hasConcept C192562407 @default.
- W2034008039 hasConcept C2780828025 @default.
- W2034008039 hasConcept C42360764 @default.
- W2034008039 hasConcept C44280652 @default.
- W2034008039 hasConcept C521977710 @default.
- W2034008039 hasConcept C66882249 @default.
- W2034008039 hasConcept C97355855 @default.
- W2034008039 hasConceptScore W2034008039C11432220 @default.
- W2034008039 hasConceptScore W2034008039C118419359 @default.
- W2034008039 hasConceptScore W2034008039C121332964 @default.
- W2034008039 hasConceptScore W2034008039C127413603 @default.
- W2034008039 hasConceptScore W2034008039C134458231 @default.
- W2034008039 hasConceptScore W2034008039C15920480 @default.
- W2034008039 hasConceptScore W2034008039C159985019 @default.
- W2034008039 hasConceptScore W2034008039C166940927 @default.
- W2034008039 hasConceptScore W2034008039C178790620 @default.
- W2034008039 hasConceptScore W2034008039C179104552 @default.
- W2034008039 hasConceptScore W2034008039C185592680 @default.
- W2034008039 hasConceptScore W2034008039C188027245 @default.
- W2034008039 hasConceptScore W2034008039C192562407 @default.
- W2034008039 hasConceptScore W2034008039C2780828025 @default.
- W2034008039 hasConceptScore W2034008039C42360764 @default.
- W2034008039 hasConceptScore W2034008039C44280652 @default.
- W2034008039 hasConceptScore W2034008039C521977710 @default.
- W2034008039 hasConceptScore W2034008039C66882249 @default.
- W2034008039 hasConceptScore W2034008039C97355855 @default.
- W2034008039 hasFunder F4320320879 @default.
- W2034008039 hasIssue "1" @default.
- W2034008039 hasLocation W20340080391 @default.