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• W2034008831 abstract "Experimental (ζ, pH) curves were used to adjust a surface complexation model describing a freshly precipitated aluminum hydroxide-NaCl electrolyte interface. Six superficial reaction constants were estimated using a non-linear program. For an aluminum hydroxide characterized by NS=1.1 sites nm −2 and PZC 8.2, the following values were obtained: pK1=6.37, pK2=10.03: amphoteric dissociation of = Al-OH groups; pK3=3.40, pK4=3.58: complexation of charged sites = Al-OH+2 and = Al-O− by Cl− and Na+ respectively; pk5 = 0.094, pK6 0.88: adsorption onto uncharged sites = Al-Oh. The last four values indicate an electrostatic adsorption of Na+ and Cl− ions onto the surface sites. An estimate of the ionic activity coefficients (γd) at the interface leads to very low values as compared with those of Debye-Hückel for a bulk solution." @default.
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• W2034008831 date "1988-01-01" @default.
• W2034008831 modified "2023-10-14" @default.
• W2034008831 title "Electrochemical modelling of freshly precipitated aluminum hydroxide-electrolyte interface" @default.
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• W2034008831 doi "https://doi.org/10.1016/0166-6622(88)80061-1" @default.
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