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- W2034042016 abstract "Contrary to earlier reports on closely related compounds, the reaction of all four diastereomers of 5α-cholestane-2,3-diol bismethanesulfonate with sodium iodide gives 5α-cholest-2-ene. The rate of the reaction decreases in the order 2α,3α > 2α 3β � 28,3α ≈ 2β,3β. The reactions of the 5α-cholestan-2- and -3-yl methanesulfonates with sodium iodide were also investigated. The relative reaction rates are explained by considering the steric effects of the substituents." @default.
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- W2034042016 date "1979-01-01" @default.
- W2034042016 modified "2023-09-23" @default.
- W2034042016 title "Steric Effects on the Iodide-Induced Elimination of 2- and 3-Methanesulfonyloxy Groups from 5α-Cholestane Derivatives" @default.
- W2034042016 doi "https://doi.org/10.1071/ch9792433" @default.
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