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- W2034043390 abstract "Isotropic proton magnetic resonance shifts of γ-picoline solvent containing some adducts of the type ML2B2, where M = Mn(II), Fe(II) and Ni(II), L = thenoyltrifluoroacetone and monothiothenoyltrifluoroacetone and B = γ-picoline, have been measured. Slow exchange rate of the base was observed evidently in Ni(II) adducts. The small contribution of the pseudo contact shift to the isotropic shifts was verified, and the observed contact shifts were discussed from the viewpoint of ligand to metal and metal to ligand spin transfers. The calculated fractions of metal to ligand α spin transfer in the three kinds of metal ions were well correlated with the numbers of unpaired electrons in t2g orbitals." @default.
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- W2034043390 date "1979-01-01" @default.
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- W2034043390 title "Isotropic PMR shifts in pyridine base adducts of Mn(II), Fe(II) and Ni(II) complexes of TTA and STTA" @default.
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- W2034043390 doi "https://doi.org/10.1016/0022-1902(79)80108-6" @default.
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