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- W2034052536 abstract "[Co{HB(C2H2N3)3}2] reacts with an excess of CuCl2 in hot water with formation of ∞2[Cu2Cl2{μ3-HB(C2H2N3)3}2 · 2 H2O] (7) or ∞3{[Cu2{μ4-HB(C2H2N3)3} (μ-OH)2]Cl · 6 H2O} (8), depending on the reaction time. 8 can also be obtained from [Cu{HB(C2H2N3)3}2] and CuCl2 in aqueous ammonia. The 2-D double-layer-type coordination polymer 7 crystallizes in the orthorhombic space group P212121. The two different Cu(II) centers in the lattice are distinguished only be the direction of the Jahn-Teller distortion. The following corresponding distances for the CuClN5 coordination sphere were found Cu1/Cu2–Cl = 2.572(2)/2.328(2), Cu1/Cu2–N = 2.585(5)/2.077(4); 2.000(4)/1.979(5); 2.100(5)/2.734(5); 2.005(4)/1.994(4); 2.024(5)/2.369(5). In the 3-D coordination polymer 8 one of the two different Cu centers is chelated by the three endodentate nitrogen donors, while the other Cu center is coordinated by three exodentate nitrogen atoms. The coordination sphere is completed in both cases by two hydroxo bridges to symmetry-related Cu centers. The metal-ligand connectivity creates infinite channels with helical walls which contain the solvated chloride anions." @default.
- W2034052536 created "2016-06-24" @default.
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- W2034052536 date "1996-09-01" @default.
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- W2034052536 title "Copper Coordination Polymers with Infinite Chloride Ion Channels and Different Directions of the Jahn‐Teller Distortion, Built from Tris(1,2,4‐triazolyl)borate as a Modified Tris(pyrazolyl)borate Ligand" @default.
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- W2034052536 doi "https://doi.org/10.1002/cber.19961290903" @default.
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