FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2034073732> ?p ?o ?g. }

• W2034073732 endingPage "2430" @default.
• W2034073732 startingPage "2421" @default.
• W2034073732 abstract "Spatial distribution of CH hydrogen atoms with reference to a six-membered carbon aromatic ring was analyzed in the crystal structures deposited in the Cambridge Structural Database (CSD). The crystal data showed the propensity that the CH hydrogen atoms lie above the center of the aromatic ring to form interatomic CH/π contacts. Investigation of the effects of the CH proton acidity on the strength and the structure of the CH/π interaction has demonstrated that the distance between the hydrogen atom and the π plane (Dpln) decreases with increase of the CH proton acidity (Dpln: CCH3 ≅ sp2-CH > sp-CH ≅ Cl2CH2 > Cl3CH), and that the C–H···π access angle (α) tends to approach 180° in the same order. Further, a negative correlation has been found between Dpln and α. The directional preferences are in accord with the property of conventional hydrogen bond, indicating a hydrogen-bond-like character of the CH/π interaction. In order to elucidate the intrinsic nature of the CH/π interaction, ab initio calculations..." @default.
• W2034073732 created "2016-06-24" @default.
• W2034073732 creator A5002230786 @default.
• W2034073732 creator A5006257544 @default.
• W2034073732 creator A5007703129 @default.
• W2034073732 creator A5017743291 @default.
• W2034073732 creator A5027178331 @default.
• W2034073732 creator A5056985907 @default.
• W2034073732 creator A5066648889 @default.
• W2034073732 creator A5090017586 @default.
• W2034073732 creator A5090450331 @default.
• W2034073732 date "2001-12-01" @default.
• W2034073732 modified "2023-09-26" @default.
• W2034073732 title "Hydrogen-Bond-Like Nature of the CH/π Interaction as Evidenced by Crystallographic Database Analyses and Ab Initio Molecular Orbital Calculations" @default.
• W2034073732 cites W1585091301 @default.
• W2034073732 cites W1968867202 @default.
• W2034073732 cites W1969291218 @default.
• W2034073732 cites W1970462616 @default.
• W2034073732 cites W1972306406 @default.
• W2034073732 cites W1974667766 @default.
• W2034073732 cites W1982712182 @default.
• W2034073732 cites W1985547429 @default.
• W2034073732 cites W1986272369 @default.
• W2034073732 cites W1990886938 @default.
• W2034073732 cites W2003732742 @default.
• W2034073732 cites W2004025836 @default.
• W2034073732 cites W2004118283 @default.
• W2034073732 cites W2018990854 @default.
• W2034073732 cites W2019515215 @default.
• W2034073732 cites W2027033103 @default.
• W2034073732 cites W2028578344 @default.
• W2034073732 cites W2036074920 @default.
• W2034073732 cites W2036668937 @default.
• W2034073732 cites W2044940178 @default.
• W2034073732 cites W2046590160 @default.
• W2034073732 cites W2048313018 @default.
• W2034073732 cites W2058121386 @default.
• W2034073732 cites W2067398027 @default.
• W2034073732 cites W2070571430 @default.
• W2034073732 cites W2074487342 @default.
• W2034073732 cites W2075089921 @default.
• W2034073732 cites W2075962697 @default.
• W2034073732 cites W2092032702 @default.
• W2034073732 cites W2110893908 @default.
• W2034073732 cites W2113718502 @default.
• W2034073732 cites W2148941593 @default.
• W2034073732 cites W2951254262 @default.
• W2034073732 cites W2952035470 @default.
• W2034073732 doi "https://doi.org/10.1246/bcsj.74.2421" @default.
• W2034073732 hasPublicationYear "2001" @default.
• W2034073732 type Work @default.
• W2034073732 sameAs 2034073732 @default.
• W2034073732 citedByCount "143" @default.
• W2034073732 countsByYear W20340737322012 @default.
• W2034073732 countsByYear W20340737322013 @default.
• W2034073732 countsByYear W20340737322014 @default.
• W2034073732 countsByYear W20340737322015 @default.
• W2034073732 countsByYear W20340737322016 @default.
• W2034073732 countsByYear W20340737322017 @default.
• W2034073732 countsByYear W20340737322018 @default.
• W2034073732 countsByYear W20340737322019 @default.
• W2034073732 countsByYear W20340737322020 @default.
• W2034073732 countsByYear W20340737322021 @default.
• W2034073732 countsByYear W20340737322022 @default.
• W2034073732 countsByYear W20340737322023 @default.
• W2034073732 crossrefType "journal-article" @default.
• W2034073732 hasAuthorship W2034073732A5002230786 @default.
• W2034073732 hasAuthorship W2034073732A5006257544 @default.
• W2034073732 hasAuthorship W2034073732A5007703129 @default.
• W2034073732 hasAuthorship W2034073732A5017743291 @default.
• W2034073732 hasAuthorship W2034073732A5027178331 @default.
• W2034073732 hasAuthorship W2034073732A5056985907 @default.
• W2034073732 hasAuthorship W2034073732A5066648889 @default.
• W2034073732 hasAuthorship W2034073732A5090017586 @default.
• W2034073732 hasAuthorship W2034073732A5090450331 @default.
• W2034073732 hasConcept C112887158 @default.
• W2034073732 hasConcept C139358910 @default.
• W2034073732 hasConcept C147597530 @default.
• W2034073732 hasConcept C178790620 @default.
• W2034073732 hasConcept C183971685 @default.
• W2034073732 hasConcept C185592680 @default.
• W2034073732 hasConcept C2781442258 @default.
• W2034073732 hasConcept C32909587 @default.
• W2034073732 hasConcept C8010536 @default.
• W2034073732 hasConceptScore W2034073732C112887158 @default.
• W2034073732 hasConceptScore W2034073732C139358910 @default.
• W2034073732 hasConceptScore W2034073732C147597530 @default.
• W2034073732 hasConceptScore W2034073732C178790620 @default.
• W2034073732 hasConceptScore W2034073732C183971685 @default.
• W2034073732 hasConceptScore W2034073732C185592680 @default.
• W2034073732 hasConceptScore W2034073732C2781442258 @default.
• W2034073732 hasConceptScore W2034073732C32909587 @default.
• W2034073732 hasConceptScore W2034073732C8010536 @default.
• W2034073732 hasIssue "12" @default.
• W2034073732 hasLocation W20340737321 @default.
• W2034073732 hasOpenAccess W2034073732 @default.
• W2034073732 hasPrimaryLocation W20340737321 @default.
• W2034073732 hasRelatedWork W1608448550 @default.

• next