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- W2034076827 abstract "The propagation process in radical polymerization of dialkyl fumarates (DRF) was investigated. The propagation rate constants (kp) for some DRFs were determined by ESR spectroscopy. It was revealed that kp increased with the introduction of a bulky tert-butyl ester group in the following order: di-tert-butyl fumarate>methyl tert-butyl fumarate>dimethyl fumarate. The absolute rate constants for meso and racemo additions were elucidated by the combination of the kp and the probability of meso addition, which was determined by 13C NMR spectroscopy." @default.
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- W2034076827 date "1991-10-01" @default.
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- W2034076827 title "Meso and racemo Additions in Propagation for Radical Polymerization of Dialkyl Fumarates II. Determination of the Absolute Rate Constants" @default.
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- W2034076827 doi "https://doi.org/10.1295/polymj.23.1249" @default.
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