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- W2034087744 abstract "Abstract We have measured the 57Fe Mossbauer spectra for the hexagonal BaFeO3−y system with different oxygen contents. The Fe sites are subdivided into two electronically nonequivalent sites, that is, one is a tetravalent site and the other a trivalent one. The Fe4+ concentration decreases not only with increase of oxygen vacancies but also with temperature. In BaFeO2.88, the magnetic order occurs at 130 K and the temperature dependence of Fe4+ concentration changes around 170 K." @default.
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- W2034087744 date "1993-04-01" @default.
- W2034087744 modified "2023-10-04" @default.
- W2034087744 title "Study on the hexagonal BaFeO3−y system by the Mössbauer effect" @default.
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- W2034087744 doi "https://doi.org/10.1016/0168-583x(93)95201-f" @default.
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