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• W2034098422 abstract "The gas-phase photooxidation of trichloroethylene (TCE) on Pt/TiO2 has been investigated. The wavelength dependence of this reaction on Pt/TiO2 shows that the addition of small amounts of platinum (≤2%) to TiO2 can enhance the photooxidation of TCE to much longer wavelengths. This result correlates with Maxwell−Garnett calculations and experimental absorption curves for Pt/TiO2 samples. Although the spectral response of Pt/TiO2 extends to longer wavelengths, Pt/TiO2 is found to be less effective in the photooxidation of gas-phase TCE upon broad-band irradiation (λ > 300 nm) compared to TiO2. It is proposed that site blocking by the Pt particles of the most active sites, Ti3+ sites, is the cause of the decreased photoactivity. In addition, it has also been determined that the photoproduct distribution changes as a function of platinum loading. Mechanisms to explain the observed effects of Pt loading on the photooxidation of TCE on Pt/TiO2 are discussed." @default.
• W2034098422 created "2016-06-24" @default.
• W2034098422 creator A5071608368 @default.
• W2034098422 creator A5079344465 @default.
• W2034098422 date "1998-01-30" @default.
• W2034098422 modified "2023-10-16" @default.
• W2034098422 title "Photooxidation of Trichloroethylene on Pt/TiO₂" @default.
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• W2034098422 doi "https://doi.org/10.1021/jp9724075" @default.
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