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- W2034102012 endingPage "812" @default.
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- W2034102012 abstract "Phosphonium ionic liquids (PhosILs), most notably tetradecyl(trihexyl)phosphonium decanoate (PhosIL-C(9)H(1)9COO), are solvents for bases such as Grignard reagents, isocyanides, Wittig reagents (phosphoranes), and N-heterocyclic carbenes (NHCs). The stability of the organometallic species in PhosIL solution is anion dependent. Small bases, such as hydroxide, react with the phosphonium ions and promote C-H exchange as suggested by deuterium-labeling studies. A method to dry and purify the ionic liquids is described and this step is important for the successful use of basic reagents in PhosIL. NHCs have been generated in PhosIL, and these persistent solutions catalyze organic transformations such as the benzoin condensation and the Kumada-Corriu cross-coupling reaction. Phosphoranes were generated in PhosIL, and their reactivity with various organic reagents was also tested. Inter-ion contacts involving tetraalkylphosphonium ions have been assessed, and the crystal structure of [(n-C(4)H(90)(4)P][CH(3)CO(2).CH(3)CO(2)H] has been determined to aid the discussion. Decomposition of organometallic compounds may also proceed through electron-transfer processes that, inter alia, may lead to decomposition of the IL, and hence the electrochemistry of some representative phosphonium and imidazolium ions has been studied. A radical derived from the electrochemical reduction of an imidazolium ion has been characterized by electron paramagnetic resonance spectroscopy." @default.
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- W2034102012 date "2008-01-04" @default.
- W2034102012 modified "2023-10-14" @default.
- W2034102012 title "Carbon-Centered Strong Bases in Phosphonium Ionic Liquids" @default.
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- W2034102012 cites W191442324 @default.
- W2034102012 cites W1963803996 @default.
- W2034102012 cites W1979091050 @default.
- W2034102012 cites W1986869409 @default.
- W2034102012 cites W1990664989 @default.
- W2034102012 cites W1994813027 @default.
- W2034102012 cites W1994963833 @default.
- W2034102012 cites W1995596954 @default.
- W2034102012 cites W2003143283 @default.
- W2034102012 cites W2003910870 @default.
- W2034102012 cites W2008849880 @default.
- W2034102012 cites W2009794410 @default.
- W2034102012 cites W2018166191 @default.
- W2034102012 cites W2020627212 @default.
- W2034102012 cites W2021908094 @default.
- W2034102012 cites W2024643871 @default.
- W2034102012 cites W2026749434 @default.
- W2034102012 cites W2032005884 @default.
- W2034102012 cites W2032053739 @default.
- W2034102012 cites W2043423092 @default.
- W2034102012 cites W2047943849 @default.
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- W2034102012 cites W2054036231 @default.
- W2034102012 cites W2056326959 @default.
- W2034102012 cites W2057235623 @default.
- W2034102012 cites W2060625108 @default.
- W2034102012 cites W2061150928 @default.
- W2034102012 cites W2068614549 @default.
- W2034102012 cites W2072934326 @default.
- W2034102012 cites W2073739546 @default.
- W2034102012 cites W2075626300 @default.
- W2034102012 cites W2084208484 @default.
- W2034102012 cites W2087266904 @default.
- W2034102012 cites W2089349480 @default.
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- W2034102012 cites W2107798664 @default.
- W2034102012 cites W2120032761 @default.
- W2034102012 cites W2121487848 @default.
- W2034102012 cites W2126454251 @default.
- W2034102012 cites W2126556152 @default.
- W2034102012 cites W2129299583 @default.
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- W2034102012 cites W2147304506 @default.
- W2034102012 cites W2153102323 @default.
- W2034102012 cites W2160194730 @default.
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- W2034102012 cites W2175551170 @default.
- W2034102012 cites W2521894265 @default.
- W2034102012 cites W2949393622 @default.
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- W2034102012 cites W4211172071 @default.
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- W2034102012 doi "https://doi.org/10.1021/jo701289d" @default.
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