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- W2034110723 abstract "The reaction of WCl6/LiAlH4 with imines, R′NCHR, gave tertiary amines, R′N(CH2R)2, and secondary amines, R′NHCHRCH2R. Isotope labeling experiments revealed that the reaction involved two types of azatungstenacyclobutanes, WNR′CHRCHR and WCHRNR′CHR, produced from the reaction of an alkylidene tungsten intermediate with the imine CN double bond. Formation of these metallacyclobutanes is highly dependent on the solvent used." @default.
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- W2034110723 date "1985-06-01" @default.
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- W2034110723 title "WCl6/LiAlH4 Promoted transformation of imines into secondary and tertiary amines" @default.
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- W2034110723 doi "https://doi.org/10.1016/0022-328x(85)80125-x" @default.
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