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- W2034111385 abstract "Photosensitized polymerization of ethylene in benzene solution has been studied at 83°C. using azoisopropane as initiator. Experiments were conducted in the concentration range from 6.5 to 28.1 wt.-% of ethylene and at pressures equal to the vapor pressure of the solutions. The apparent order of reaction with respect to the monomer varies from 1 to 1.5. The intensity exponent exceeds 0.5 and increases with increasing initiator concentration. Chain transfer constants with monomer, solvent, and initiator have been determined. Their values are: k4/k2 = 5 x 10−4, ks/k2 = 2 x 10−3, and kK/k2 = 0.5 ± 0.1, respectively." @default.
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- W2034111385 date "1959-07-01" @default.
- W2034111385 modified "2023-10-16" @default.
- W2034111385 title "The kinetics of radical polymerization of ethylene. I. General kinetics" @default.
- W2034111385 doi "https://doi.org/10.1002/pol.1959.1203813322" @default.
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