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• W2034115927 startingPage "661" @default.
• W2034115927 abstract "A neutron-diffraction experiment (ensuremath{lambda}=0.704 Ar{}) has been performed for the first time on liquid arsenic above the triple point. The coordination number (Z=3) does not change through the semimetal-to-semiconductor transition on melting. This is in sharp contrast to the elemental semiconductors (Si,Ge) that undergo a semiconductor-to-metal transition upon melting, accompanied by an increase (4ensuremath{rightarrow}6.4) of the coordination number. The nonmetallic behavior of As, which has a half-filled p band, can be understood as a Peierls distortion in the p-bonding mechanism (three p-p bonds are reinforced; the others are considerably weakened)." @default.
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• W2034115927 date "1987-08-10" @default.
• W2034115927 modified "2023-09-26" @default.
• W2034115927 title "Structure of liquid As: A Peierls distortion in a liquid" @default.
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• W2034115927 doi "https://doi.org/10.1103/physrevlett.59.661" @default.
• W2034115927 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/10035838" @default.
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