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• W2034117374 abstract "The dictyostatins are powerful microtubule-stabilizing agents that have shown antiproliferative activity against a variety of human cancer cell lines. Two highly active analogs of dictyostatin, 25,26-dihydrodictyostatin and 25,26-dihydro-6-epi-dictyostatin, were prepared by a new streamlined total synthesis route. Three complete carbon fragments were prepared to achieve maximum convergency. These were coupled by a Horner-Wadsworth-Emmons reaction sequence and an esterification. A late stage Nozaki-Hiyama-Kishi reaction was then used to form the 22-membered macrolide. The stereoselectivity of this reaction depended on the configurations of the nearby stereocenter at C6." @default.
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• W2034117374 date "2011-10-05" @default.
• W2034117374 modified "2023-10-13" @default.
• W2034117374 title "Efficient syntheses of 25,26-dihydrodictyostatin and 25,26-dihydro-6-<i>epi</i>-dictyostatin, two potent new microtubule-stabilizing agents" @default.
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• W2034117374 doi "https://doi.org/10.3762/bjoc.7.161" @default.
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