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• W2034121950 startingPage "299" @default.
• W2034121950 abstract "The non-contact atomic force microscopy (nc-AFM) images of the single alkanethiolate molecules embedded in the bicyclo[2,2,2]octylmethylthiolate (BCO) self-assembled monolayer (SAM) are simulated using the all-atom empirical force field model. The tip is modeled by the chemically inactive and unpolarized carbon nanocone apex. When the alkyl chain is longer than the BCO matrix, the protruded chain is observed to be lower than its actual height. Even if the alkyl chain has a similar height to the BCO, the former is observed to be slightly lower than the latter. These findings indicate that even when the chemical and electrostatic interactions are not relevant for imaging, the nc-AFM images do not always give true topographical information of the molecules under the tip. [DOI: 10.1380/ejssnt.2006.299]" @default.
• W2034121950 created "2016-06-24" @default.
• W2034121950 creator A5018306514 @default.
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• W2034121950 date "2006-01-01" @default.
• W2034121950 modified "2023-10-16" @default.
• W2034121950 title "Molecular Structure Alters Apparent Height in nc-AFM Images of Alkanethiolate Embedded in Matrix" @default.
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• W2034121950 doi "https://doi.org/10.1380/ejssnt.2006.299" @default.
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