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• W2034128210 endingPage "827" @default.
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• W2034128210 abstract "Li-alloys with mobile Li are interesting anode materials for rechargeable organic electrolyte Li-batteries. Their obvious disadvantages over anodes of metallic Li - lower energy and power densities - may be overbalanced by their advantages - lower rates of corrosion and passivation. Thermodynamics and transport properties of many intermetallic phases containing mobile Li have been investigated carefully and there are several candidates which meet reasonable energy density and power density requirements - so long as only bulk properties are regarded. However, limitations of practical Li-alloy anodes are mainly related with surface problems: surface filming of alloys LixM by decomposition products of the electrolyte affects the contact LixM/electrolyte as well as the contact LixM/grid. Moreover, the permanent volume changes of LixM/M during charge/discharge cycling cause considerable “crumbling” of the active mass. This paper shows up ways how to tackle the above-mentioned problems: chemically inert surfactants minimize surface filming; adhesion LixM/grid can be improved by an alloy zone “grid material + M” between grid and active mass; “crumbling” of LixM during cycling can be reduced by using composites of LixM + reinforcing component as active masses." @default.
• W2034128210 created "2016-06-24" @default.
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• W2034128210 date "1986-01-01" @default.
• W2034128210 modified "2023-10-13" @default.
• W2034128210 title "Binary and ternary Li-alloys as anode materials in rechargeable organic electrolyte Li-batteries" @default.
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• W2034128210 doi "https://doi.org/10.1016/0167-2738(86)90270-5" @default.
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