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• W2034128947 abstract "Described in this study is a conceptually new class of five-fold-symmetric cavity-containing planar pentameric macrocycles with their interior decorated by five convergently aligned, properly spaced carbonyl oxygen atoms. These cation-binding oxygens enclose a hydrophilic lumen of 2.85 Å in radius and thus display high-affinity binding toward alkali metal cations, and possibly many other cations, too. Arising from their high-affinity recognition of metal ions, these planar macrocycles form cation- or ion-pair-induced one-dimensional columnar aggregates, and subsequently fascinating fibrillation results." @default.
• W2034128947 created "2016-06-24" @default.
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• W2034128947 date "2011-08-16" @default.
• W2034128947 modified "2023-09-25" @default.
• W2034128947 title "Five-Fold-Symmetric Macrocyclic Aromatic Pentamers: High-Affinity Cation Recognition, Ion-Pair-Induced Columnar Stacking, and Nanofibrillation" @default.
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• W2034128947 doi "https://doi.org/10.1021/ja206457b" @default.
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