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• W2034133571 abstract "A mass-spectrometric study of the thermal decomposition of Group II and VI alkyls involved in ZnTe growth by metal-organic chemical vapour deposition (MOCVD) is reported. The pyrolysis of diethylzinc (Et2Zn) and diethyltellurium (Et2Te) alone and together were followed with the change of the inlet partial pressure ratio (R= Te/Zn = 1 and 5). Under He and H2, the thermal decomposition of Et2Zn organometallic species leads to the formation of n-C4H10, C2H4 and C2H6. The pyrolysis of Et2Te produces ethene in excess of other hydrocarbons. For co-decomposition in an He atmosphere, pyrolysis curves as a function of temperature, with R= 1 show that the temperature corresponding to the half-decomposition ratio (T50) of Et2Te is lowered by 25 °C relative to that of Et2Te alone. For R= 5, the T50 of Et2Zn is increased by 30 °C relative to that of the precursor alone. The kinetics of decomposition of Et2Zn and Et2Te alone showed no thermal hysteresis, whereas a strong hysteresis loop between heating and cooling of the susceptor was recorded during the co-decomposition. The dependence of these effects on R and temperature are discussed in relation to surface reactions." @default.
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• W2034133571 date "1992-01-01" @default.
• W2034133571 modified "2023-10-17" @default.
• W2034133571 title "Mass-spectrometric study of thermal decomposition of diethylzinc and diethyltellurium" @default.
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• W2034133571 doi "https://doi.org/10.1039/jm9920200923" @default.
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