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- W2034134005 abstract "Simultaneous isomerization and cracking of n-hexane has been studied over a commercial 0.35 wt% PtAl2O3 catalyst at 420 to 450 °C, a total pressure of 10.5 bar and a hydrogen/hydrocarbon partial pressure ratio of 20 in a fixed-bed reactor. Under these reaction conditions the individual reactions were assumed to be pseudomonomolecular and the method of Wei and Prater was used to obtain isomerization and cracking rate constants. The proposed reaction scheme consisted of a reversible three-component system, namely isomerization of n-hexane to 2-methylpentane and 3-methylpentane, and three irreversible steps, namely CC bond rupture of n-hexane, 2- and 3-methylpentane yielding C1C5 alkanes, and isomerization to 2,2- and 2,3-dimethylbutane. From measurements of the equilibrium composition, an artificial straight line reaction path, and a curved reaction path, the pseudomonomolecular reaction rate constant matrix was obtained." @default.
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- W2034134005 date "1979-10-01" @default.
- W2034134005 modified "2023-09-27" @default.
- W2034134005 title "Kinetics of simultaneous isomerization and cracking of n-hexane over Pt/Al2O3" @default.
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- W2034134005 doi "https://doi.org/10.1016/0021-9517(79)90075-7" @default.
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