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- W2034135091 abstract "We report here the first extensive study of the conformational transitions of a diblock polyampholyte (made of two symmetric blocks, one positively, the other negatively charged). Results are obtained by means of a Monte Carlo simulation on a square (resp. cubic) lattice in 2 (resp. 3) dimensions, using the Bond Fluctuation algorithm together with a Multiple Histogram method. In both dimensions, an early (i.e. high temperature) transition is observed which is shown to correspond to the pairing of both blocks together, resulting in a `super-coil', each `super-monomer' being a dipole made of one positive and one negative monomer. Phenomenological characteristics of this pairing transition are given and its specificity is outlined. A second transition is also observed at a lower temperature in both dimensions. However, whereas it is a mere coil-globule transition of the `super-coil' in three dimensions, it happens to be rather a folding in two dimensions because of topological constraints." @default.
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- W2034135091 date "1999-07-01" @default.
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- W2034135091 title "Conformational transitions of a diblock polyampholyte in 2 and 3 dimensions" @default.
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- W2034135091 doi "https://doi.org/10.1016/s0375-9601(99)00341-2" @default.
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