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• W2034136955 abstract "The title complex, [Co(C12H8FN2O)3]·3H2O, has been synthesized for the first time. The complex comprises three bidentate ligands containing the pyridine-2-carbox­amide stem. The distorted octahedral coordination around the Co atom is formed via the pyridine (py) N atom and the deprotonated amide N atom of each ligand, with the three pyridine rings in a meridional arrangement. For each ligand, the pyridine ring and the carbonyl group are nearly coplanar, with torsion angles in the range 0.4 (3)–4.8 (4)°. The Co—Npy distances [1.9258 (16)–1.9656 (17) Å] are shorter than the corresponding Co—Namide distances [1.9372 (17)–1.9873 (15) Å]. In addition, the Co—Npy distances are closely related to the magnitudes of the chelate angles, a shorter Co—Npy distance corresponding to a larger angle. Five intermolecular hydrogen bonds, involving carbonyl O atoms of the ligands and lattice water mol­ecules, lead to the formation of a mesh structure." @default.
• W2034136955 created "2016-06-24" @default.
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• W2034136955 date "2004-04-21" @default.
• W2034136955 modified "2023-09-27" @default.
• W2034136955 title "Tris[<i>N</i>-(4-fluorophenyl)pyridine-2-carboxamidato-κ²<i>N</i>,<i>N</i>′]cobalt(III) trihydrate: a novel meridional complex" @default.
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• W2034136955 doi "https://doi.org/10.1107/s0108270104005803" @default.
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