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- W2034138300 abstract "Abstract An expression for the dynamic electrophoretic mobility μ of spherical colloidal particles with infinitesimally thin double layers ( κa →∞ where κ is the Debye–Huckel parameter and a is the particle radius) in concentrated suspensions in an oscillating electric field is derived on the basis of Kuwabara's cell model [J. Phys. Soc. Jpn. 14 (1959) 527] and the method of Lowenberg and O'Brien [J. Colloid Interface Sci. 150 (1992) 158]. The result agrees with the large κa limiting form of the dynamic mobility obtained previously by solving the full electrokinetic equations [J. Colloid Interface Sci. 195 (1997) 137]. The dynamic mobility depends on the frequency ω of the applied electric field and the particle volume fraction φ as well as on the reduced particle radius a and the zeta potential ζ , in contrast to the static case ( ω →0), in which case the mobility in the limit of κa →∞ is given by Smoluchowski's formula independent of φ and a . It is also found that the ω dependence of the mobility magnitude becomes less as φ increases, that is, the dynamic mobility at any ω approaches Smoluchowski's static mobility as φ increases." @default.
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- W2034138300 date "1999-04-01" @default.
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- W2034138300 title "Dynamic electrophoretic mobility of spherical colloidal particles with thin electrical double layers in concentrated suspensions" @default.
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- W2034138300 doi "https://doi.org/10.1016/s0927-7757(98)00522-6" @default.
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