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• W2034140709 startingPage "1198" @default.
• W2034140709 abstract "Exceptionally high affinity for cesium cations was achieved in aqueous solution using two enantiopure cryptophanes. Complexation of cesium was evidenced by 133Cs NMR spectroscopy and by electronic circular dichroism (ECD). Binding constants as high as 6 × 109 M–1 have been measured by isothermal titration calorimetry (ITC). Very strong complexation of rubidium cations (K ∼106 M–1) has also been measured. Chiral hosts allowed the detection of the two cations at low concentrations (μM) using ECD." @default.
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• W2034140709 date "2012-01-10" @default.
• W2034140709 modified "2023-10-16" @default.
• W2034140709 title "High Affinity of Water-Soluble Cryptophanes for Cesium Cations" @default.
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• W2034140709 doi "https://doi.org/10.1021/jo202259r" @default.
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